an accurate empirical correlation to estimate sonic speed of ionic liquids

نویسندگان

mohammad hasan vakili

ehsan sanjari

zahra jali

چکیده

in recent years there has been a great deal of attention paid by researchers in investigating ionic liquids (ils) mainly due to the tremendous potential that ionic liquids have in reaction and separation technology. sonic speed is an important thermodynamic property of ionic liquids (ils) and always chosen as a source to determine other properties. a database for the sonic speed of pure ils created by collecting experimental data from literature covering the period from 2005 to 2013 is presented. in this study, based on sonic speed experimental data, for the first time the relationship between boiling temperature, reduced temperature and pressure for 2198 data of 29 ionic liquids covering wide ranges of temperature, pressure, and sonic speed has been examined. in results, a 6-parameter model with ability for predicts the sonic speed of ionic liquids is presented. the obtained model has an average absolute relative deviation (aard%) of 1.30%,a determination coefficient (r2) of 0.987, and a root mean square error (rsmd) of 1.85.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

An Accurate Empirical Correlation to Estimate Sonic speed of Ionic Liquids

In recent years there has been a great deal of attention paid by researchers in investigating ionic liquids (ILs) mainly due to the tremendous potential that ionic liquids have in reaction and separation technology. Sonic speed is an important thermodynamic property of ionic liquids (ILs) and always chosen as a source to determine other properties. A database for the sonic speed of pure ILs cre...

متن کامل

An Accurate Correlation to Estimate Saturated Molar Volume of Liquids

There are a number of techniques available to estimate saturated-liquid molar or specific volumes or densities of liquids. In this study, a new empirical correlation is presented to calculate volume of saturated liquids as a function of critical volume, reduced temperature and acentric factor. An optimization algorithm is utilized to obtain unknown parameters of this correlation by fitting them...

متن کامل

an accurate correlation to estimate saturated molar volume of liquids

there are a number of techniques available to estimate saturated-liquid molar or specific volumes or densities of liquids. in this study, a new empirical correlation is presented to calculate volume of saturated liquids as a function of critical volume, reduced temperature and acentric factor. an optimization algorithm is utilized to obtain unknown parameters of this correlation by fitting them...

متن کامل

An Improvement to the Properties of GAP Binder with Energetic Ionic Liquids

Glycidyl azide polymer (GAP) is used as a binder in the propellants. Energetic ionic liquids are used as a plasticizer to correct the properties of polymer. In this study, first ionic liquid was bonded to the GAP by certain amount and then the energetic anions of nitrate (NO3) and azide (N3) were used to exchange anion. FTIR analyses confirm accurately anions exchange. DSC, viscometer and heat ...

متن کامل

Empirical Correlations and an Artificial Neural Network Approach to Estimate Saturated Vapor Pressure of Refrigerants

The examination of available vapor pressure data in the case of the methane, ethane, propane and butane halogenated refrigerants, allowed recommendations of standard equations for this property. In this study, three new models include a general correlation; a substance-dependent correlation and an artificial neural network (ANN) approach have been developed to estimate the saturated vapor press...

متن کامل

Determining an accurate method to estimate GFR in renal transplant recipients with stable serum creatinine levels

Introduction:Detecting renal allograft dysfunction early will allow timely diagnosis and treatment. There is no objective recommendation by national kidney societies for glomerular filtration rate (eGFR) estimation in post-transplant setting. 99mTc-DTPA Technetium-99m Diethylene triamine penta acetic acid) renogram can identify early renal dysfunction much before ser...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
physical chemistry research

ناشر: iranian chemical society

ISSN 2322-5521

دوره 3

شماره 2 2015

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023